Ni-Alloys Key to Ultra-Supercritical Coal Plants’ Future

In the relentless pursuit of cleaner, more efficient energy, the global power industry is pushing the boundaries of technology. At the heart of this quest lies the advanced ultra-supercritical (A-USC) coal-fired power plant, a next-generation marvel designed to operate at unprecedented steam temperatures and pressures, around 700°C. However, this leap forward brings with it a formidable challenge: the harsh service environment that threatens the very components designed to harness this power.

Enter Ni-base alloys, the unsung heroes of high-temperature corrosion resistance. As traditional ferritic/martensitic heat-resistant steels and austenitic stainless steels falter in the face of such extreme conditions, Ni-base alloys stand firm, offering a glimmer of hope for the safe operation of A-USC boilers. But how do these alloys fare in the corrosive dance of coal ash and flue gas? This is the question that Dr. Du Lingxiao, from the School of Materials Science and Engineering at Nanchang Hangkong University, has set out to answer.

Dr. Du’s research, published in the journal ‘Cailiao gongcheng’ (translated to ‘Materials Engineering’), delves into the intricate world of high-temperature corrosion, focusing on the impact of corrosive gases and salts on the protective oxide film that forms on Ni-base alloys. “The thermal growth of this CrO3 protective film is crucial for the longevity of these alloys in A-USC environments,” Dr. Du explains. Her work highlights the role of corrosive gases like CO2, H2O, and SO2, as well as sulfate salts, in this process. But the story doesn’t end there.

The future of A-USC technology may also involve biomass combustion, which introduces a new set of challenges. “The effect of oxide particulates in coal ash, Cl-containing gases, and molten KCl salts resulting from biomass combustion on the high-temperature corrosion behavior of Ni-base alloys is a key direction for future research,” Dr. Du notes. This opens up a new frontier in the quest for cleaner, more efficient energy, one that could see biomass and coal working in tandem to power our future.

The implications of Dr. Du’s research are far-reaching. As the energy sector continues to evolve, the need for materials that can withstand extreme conditions will only grow. Ni-base alloys, with their superior creep strength and corrosion resistance, could well be the key to unlocking the full potential of A-USC technology. But to get there, we need to understand how these alloys behave in the real world, and that’s exactly what Dr. Du’s work is helping us do.

As we stand on the cusp of a new era in energy production, it’s clear that the path forward won’t be easy. But with researchers like Dr. Du leading the way, we can be confident that we’re moving in the right direction. The future of energy is bright, and it’s powered by innovation, determination, and a whole lot of science.

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